Alumina production (1)

(A) Overview 1. Properties of aluminum oxide of the formula A1 2 O 3; molecular weight 102; mp 2050 deg.] C; melting heat 21318 (25080) J / mol; density of 3.3-4.09 / cm 3; a boiling point of 2980 deg.] C; heat of vaporization 49282J/mol.
Aluminum has nine crystal forms: α, β, γ, δ, θ, κ, χ, η, ρ.
Some phases of hydrated alumina and alumina have strong chemical activity, can be dissolved in acid, and can also be dissolved in lye; while others have strong chemical stability (such as diaspore and alpha). -A1 2 O 3 ).
2. Quality Standards for Alumina The quality standards YB814-75 specified in China are shown in Table 1.

Table 1 Quality Standards for Alumina

Product level

Code

Chemical composition /%

Al 2 O 3 >

Impurity content <

SiO 2

Fe 2 O 3

Na 2 O

Burning down

First level

Al 2 O 3 -1

98.6

0.02

0.03

0.5

0.8

Secondary

Al 2 O 3 -2

98.5

0.04

0.04

0.55

0.8

Third level

Al 2 O 3 -3

98.4

0.06

0.04

0.6

0.8

Level four

Al 2 O 3 -4

98.3

0.08

0.05

0.6

0.8

Five levels

.Al 2 O 3 -5

98.2

0.1

0.05

0.6

1

Six levels

Al 2 O 3 -6

97.8

0.15

0.06

0.7

1.2

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For countries with sand-like alumina, China has its own standards: China proposes the following indicators: particle size less than 44μm ≤ 15%; specific surface area ≥ 35m 2 / g; α-A1 2 O 3 content 20% - 35%.
The chemical composition (%) is as follows:
A1 2 O 3 SiO 2 Fe 2 O 3 Na 2 O Burning TiO 2 V 2 O 5 ZnO P 2 O5
≥98.5 ≤0.04 ≤0.04 ≤0.55 ≤1.0 <0.005 <0.003 <0.005 <0.003
China's specified aluminum hydroxide quality standard GB4294-84 is shown in Table 2.

Table 2 Quality Standards for Aluminum Hydroxide

Product level

Code

Chemical composition /%

With water /%

Al 2 O 3 >

Impurity content <

SiO 2

Fe 2 O 3

Na 2 O

Burning down

First level

Al ( OH ) 3 -1

64

0.03

0.03

0.45

35

<15.0

Secondary

Al ( OH ) 3 -2

64

0.03

0.03

0.45

35

<15.0

Third level

Al ( OH ) 3 -3

63.5

0.1

0.05

0.5

35

<15.0

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